Crystallization induction time
WebThe temperature dependence of the crystallization induction time (τ 0 (T)) is a function of the thermodynamic activation barrier and the frequency of "attempted jumps" (1/τ α (T)) to overcome the barrier. Even though the four model compounds exhibited very similar molecular mobility (relaxation time) over a wide range of temperatures, their ... WebApr 14, 2024 · Induction time of crystallization depends on the cooling rate. Investigations found that EVA will grow by the hang-wall model at the air-liquid contact line interface, or by extrude-bubble growth at any site on the liquid surface in a beaker by supersaturation formation. Rapid EVA crystallization was interpreted as the introduction of space ...
Crystallization induction time
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WebFeb 4, 2024 · Crystallization is a collection of the subprocesses of crystal primary nucleation, crystal growth, secondary nucleation and agglomeration, which are all governed by the prevailing supersaturation as well as other parameters. The rates of these … WebThe most important thermodynamic property is the solubility, and the key kinetic properties are the metastable zone width (MSZW) and the induction time. For antisolvent crystallization the solubility must be determined across a range of solvent compositions, as the solvent composition is the parameter which is changed to generate supersaturation.
WebAug 30, 2024 · The induction time is inversely proportional to the crystallization rate: τ = 1/J (Schukin et al. 2016). Therefore, specific surface energy σ was calculated based on the dependence of the induction time on supersaturation. ... There are two pronounced portions in all experimental dependences of the optical density on the crystallization … WebIn this work, new Ge-containing Fe-based nanocrystalline alloys with the composition of Fe80.2Si3B12-xP2Nb2Cu0.8Gex (x = 0, 1, 2 at.%) were developed, and the effects of Ge content on the magnetic and crystallization processes of the alloys were investigated. The addition of Ge extends the annealing window of the present Fe-based alloys, which …
WebJul 2, 2024 · Adding FHPKO to CBS increased the crystallization rate with a decrease in crystallization induction time but did not increase the heat resistance. In contrast, all KSF-CBS blends exhibited higher heat resistance than CBS and crystallized into β' form, a preferred polymorph for fats used in compound chocolate. WebMar 1, 2024 · The induction time during crystallization process is the time between a supersaturated solution reaching to the onset of nucleation [4]. Therefore, the …
WebAt the highest supersaturation ratio of 1.39, the induction time was independent of the calorimetric power once a threshold value of around 1.5 W was reached. Above this power value, the induction time was …
WebInvestigation of the induction time for CaCO3 formation The induction time in the absence and presence of Cu2+ at flow rate of 20 mL/min can be seen in Figure 2. It shows that … ttcar key serviceWebApr 29, 2024 · The time–temperature superposition of PEEK 450G; the frequency-scale shift factor (a T) and modulus-scale shift factor (b T); time–temperature protocol to monitor the isothermal crystallization induction time; an illustration to define crystallization induction time; the rheological induction times obtained at T c = 322. 325, and 328 °C ... ttc april 2022 board meetingWebInvestigation of the induction time for CaCO3 formation The induction time in the absence and presence of Cu2+ at flow rate of 20 mL/min can be seen in Figure 2. It shows that the higher concentration of Cu2+ was added in the solution, the longer induction time was achieved. For 1.00 and 10.00 ppm concentration of Cu2+, the induction time ... ttc arrow rdWebMay 3, 2013 · Smejkal et al. 6 found that the induction time for crystallization of lysozyme in a stirred crystallizer was substantially shorter compared to an experiment in a nonagitated microbatch. phoebe teareWebAug 7, 2024 · Crystallization induction time was evaluated using a UV-2501 PC UV-VIS (Shimadzu, Kyoto, Japan) spectrophotometer connected to a CPS-240A thermoelectrically temperature controlled cell holder (Shimadzu). In particular, aliquots of 2 mL of molten oleogel (heating above melting point at least 10 min) were poured into disposable plastic … phoebe teaching joey guitarWebThe induction time is defined as the time interval between to the formation of an appreciable amount of the solid phase and the initial moment of supersaturation of … phoebe teamWebIt can be measured experimentally to describe the time required for the formation of an observable change in the crystallization system from the starting point of supersaturation. Figure 5 shows the induction time measurement of AM in WSC solution. The concentration of AM in the water rapidly decreased for one minute due to the crystal nuclei ... phoebe teaching joey french